HomeMy WebLinkAboutSAFETY DATA SHEET - 22-00039 - Rexburg Idaho LDS Temple - RemodelSDS Number: 4800001 SAP Number: 9700050921 Revision Date: 5/4/2021
24 Hour Emergency Phone Numbers
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Safety Data Sheet Center:
O
1.800-535-5053 � 1-352352-323-35003500
NOTE: The National ResponseCenter emergency
numbers to be used only in the event of chemical
O emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this SDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this SDS are further described in Section 16.
1. Identification
Product Name: Low GWP Polyurethane Spray Foam A Side Revision Date:
5/4/2021
Product UPC Number.
Call Customer Service Supercedes Date: 3/15/2021
Manufacturer: DAP Products Inc. Product Use/Class: Foam Sealant/Adhesive
2400 Boston Street Suite 200 SDS No: 4800001
Baltimore, MD 21224-4723
888-327-8477 (non - emergency matters) Preparer: Regulatory and Environmental
Affairs
BOB Coordinator: MSDS@dap.com
Emergency Telephone:
Transportation: 1-800-535 -5053
1-352-323-3500
Poison Control: 1-800-222-1222
2, Hazards Identification
GHS Classification
Acute Tox. 4 Inhalation, Carc. 2, Eye Init. 2, Gas under Pressure, Comp. Gas, Resp. Sens. 1, Skin brit. 2, Skin Sens. 1, STOT RE
2, STOT BE 3 RTI
Symbol(s) of Product
<>
Signal Word
Danger
GHS HAZARD STATEMENTS
Compressed Gas H280
Skin Irritation, category 2 H315
Contains gas under pressure; may explode if heated.
Causes skin irritation.
Page 1 16
SDS Number: 4800001
Skin Sensitizer, category 1
SAP Number: 9700050921 Revision Date: 5/4/2021
Eye Irritation, category 2
H317 May cause an allergic skin reaction.
H319
Acute Toxicity, Inhalation, category 4
Causes serious eye irritation.
H332 Harmful if inhaled.
Respiratory Sensitizer, category 1
STOT, single exposure, category 3, RTI
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335
Carcinogenicity, category 2
May cause respiratory irritation.
H351
STOT, repeated exposure, category 2
Suspected of causing cancer.
H373 May cause damage to organs through prolonged or
repeated exposure.
GHS LABEL PRECAUTIONARY STATEMENTS
P201
Obtain special instructions before use.
P260
P264
Do not breathe dust/fume/gas/misttvapours/spray.
Wash thoroughly after handling.
P271
Use only outdoors or in a well -ventilated area.
P272
P280
Contaminated work clothing should not be allowed out of the workplace.
P281
Wear protective gloves/protective clothing/eye protection/face protection.
P284
Use personal protective equipment as required.
P302+P352
[In case of inadequate ventilation] wear respiratory protection.
P304+P340
IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P312
P321
Call a POISON CENTER or doctor/physician if you feel unwell.
P332+P313
Specific treatment (see ... on this label).
If skin Irritation occurs: Get medical advice/attention.
P333+P313
P337+P313
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
P342+P311
P362
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P403+P233
Take off contaminated clothing.
P405
Store in a well -ventilated place. Keep container tightly closed.
Store locked up.
P410+P403
Protect from sunlight. Store in a well -ventilated place.
P501
Dispose of contents/container to ...
GHS SDS PRECAUTIONARY STATEMENTS
P363 Wash contaminated clothing before reuse.
3C0
mposition/Information on Ingredients
Chemical Name CAS -No. Wt_% GHS Symbols
Polymeric diphenylmethane diisocyanate 9016-87-9 45-70 GHS07
4,4'-Methylene diphenyl diisocyanate (MDI) 101-68-8 10-30 GHS07-GHS08
Trans-1,3,3,3-Tetrafluoroprop-l-ene 29118-24-9 7-13 No Information
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First -aid Measures
GHS Statements
H332
H315-317-319-332-334-335-351
-373
No Information
FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is
experienced, get medical attention immediately.
FIRST AID - SKIN CONTACT: Wash skin with soap and water for 15 minutes. Get medical aid if symptoms persist. Use a rag to
remove excess foam from skin and remove contaminated clothing. Use of a solvent, such as acetone (nail polish remover) or mineral
spirits, may help in removing uncured foam residue from clothing or other surfaces (avoid eye contact). Cured foam may be physically
removed by persistent washing with soap and water. If irritation develops, use mild skin cream. If irritation persists, obtain medical
attention.
FIRST AID - EYE CONTACT: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
FIRST AID - INGESTION: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
5. Fire -fighting Measures
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may burst if exposed to extreme heat or fire. Containers may
Page 2 / 6
SDS Number: 4800001 SAP Number: 9700050921 Revision Date: 5/4/2021
explode if exposed to extreme heat.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus pressure -demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
EXTINGUISHING MEDIA: Alcohol Foam, Carbon Dioxide, Dry Chemical, Water Spray or Fog, Water
16. Accidental Release Measures I
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Use
personal protective equipment as necessary. Read all product instructions before using. Personal protective equipment should
include impervious gloves, protective eye wear, and suitable work clothes. Scrape up dried material and place into containers.
Uncured product is very sticky, so carefully remove the bulk of the foam by scraping it up and then immediately remove residue with a
rag and solvent such as polyurethane cleaner, mineral spirits, acetone (nail polish remover), paint thinner, etc. Once the product has
cured, it can only be removed physically by scraping, buffing, etc. Dispose as plastic waste (foam plastic) in accordance with all
nnnlicable guidelines and regulations.
HANDLING: KEEP OUT OF REACH OF CHILDRENIDO NOT TAKE INTERNALLY. Make sure nozzle is directed away from yourself
prior to discharge. Keep away from open flames, hot surfaces and sources of ignition. Wear appropriate personal protection. Avoid
breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Ensure fresh air entry during
application and drying. Wash thoroughly after handling. Contains isocyanates. See information supplied by the manufacturer.
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with
Isocyanates.
STORAGE: Store away from sources of ignition and heat. Protect material from direct sunlight. Keep containers tightly closed in a
dry, cool and well -ventilated place. Do not store at temperatures above 120 °F (49 °C). Store containers away from excessive heat
and freezing. Store away from caustics and oxidizers.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING
Polymeric diphenylmethane diisocyanate N.E. N.E. N.E. N.E.
4,41-Methylene dlphenyl diisocyanate 0.005 ppm TWA N.E. N.E. 0.02 ppm Ceiling, 0.2
(MDI) Methylene bisphenyl mg/m3 Ceiling
isocyanate (MDI)
Trans-1,3,3,3-Tetrafluoroprop-l-ene N.E. N.E. N.E. N.E.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Suppliers Recommendation
Sk = Skin Sensitizer N.E. = Not Established
Personal Protection
0 RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. If concentrations
exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where the
protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. A respiratory
protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use.
0 SKIN PROTECTION: Wear nitrile, neoprene, or natural rubber gloves.
0 EYE PROTECTION: Goggles or safety glasses with side shields.
0 OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron if body contact may occur.
Page 3 / 6
SDS Number: 4800001 SAP Number: 9700050921 Revision Date: 5/4/2021
HYGIENIC PRACTICES: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re -use.
and Chemical Properties
Appearance:
Odor:
Density, g/cm3:
Freeze Point,"C:
Solubility in Water:
Decomposition Temperature, °C:
Bolling Range, "C:
Minimum Flash Point, °C:
Evaporation Rate:
Vapor Density:
Combustible Dust:
Cream
Slight Solvent
1.22 - 1.22
Not Established
Not Established
Not Established
N.A. - N.A.
N.A.
Faster Than n-Butyl Acetate
Heavier Than Air
Does not support combustion
Physical State:
Foam
Odor Threshold:
Not Established
PH:
Not Applica ble
Viscosity (mPa.$):
Not Aplicable
Partition Coeff., n-octanol/water:
Not Established
Explosive Limits, %:
N.E. - N.E.
Auto -Ignition Temperature, "C
Not Established
Vapor Pressure, mmHg:
Not Established
Flash Method:
Not Applicable
Flammability, NFPA:
Non -Flammable
(See "Other information" Section for abbreviation legend)
(If product is an aerosol, the flash point stated above is that of the propellant.)
10. Stability and Reactivity
STABILITY: Stable under recommended storage conditions.
CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Incompatible with strong bases and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e., COx, NOx.
11. Toxicological Information
EFFECT OF OVEREXPOSURE - INHALATION: Vapors may be irritating to eyes, nose, throat, and lungs. Inhalation of high
concentrations may cause headache, nausea, and dizziness.
EFFECT OF OVEREXPOSURE - SKIN CONTACT: May cause sensitization by skin contact. May cause localized irritation,
reddening or swelling. Prolonged or repeated exposure may lead to sensitization and/or contact dermatitis. This product has strong
adhesive -like characteristics and will adhere aggressively to skin and other surfaces. if accidental contact occurs, follow the
appropriate first -aid procedure described in Section 4 of this SIDS.
EFFECT OF OVEREXPOSURE - EYE CONTACT: Direct eye contact may cause irritation. Mist and vapors may cause eye irritation.
Foam contact can cause physical damage due to adhesive character.
EFFECT OF OVEREXPOSURE - INGESTION: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
CARCINOGENICITY: Limited evidence in experimental animals.
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated or prolonged exposure may cause respiratory system damage.
Repeated contact may cause allergic reactions in very susceptible persons.
PRIMARY ROUTE(S) OF ENTRY., Skin Contact, Inhalation, Eye Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS -No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
9016-87-9 Polymeric diphenyimethane diisocyanate 49000 mg/kg Rat >9400 mg/kg Rabbit N.I.
101-68-8 4,4'-Methylene diphenyl diisocyanate (MDI) 31600 mg/kg Rat 9400 mg/kg Rabbit N.I.
29118-24-9 Trans-1,3,3,3-Tebafluoroprop-l-ene N.I. N.I. N.I.
N.I. = No Information
Page 416
SIDS Number: 4800001 SAP Number: 9700050921 Revision Date: 5/4/2021
12, Ecological Information
ECOLOGICAL INFORMATION: No Information
13. Disposal Information
DISPOSAL INFORMATION: Contents under pressure. Dispose of material in accordance with all federal, state and local regulations.
State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for properwaste disposal
is with the owner of the waste. Liquids cannot be disposed of in a landfill. Before disposing of containers, relieve container of any
remaining product and pressure. Empty cylinders, once relieved of all pressure, can be disposed of as non -hazardous waste.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material and remove with inert absorbent.
Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Use
personal protective equipment as necessary. Read all product instructions before using. Personal protective equipment should
include impervious gloves, protective eye wear, and suitable work clothes. Scrape up dried material and place into containers.
Uncured product is very sticky, so carefully remove the bulk of the foam by scraping it up and then immediately remove residue with a
rag and solvent such as polyurethane cleaner, mineral spirits, acetone (nail polish remover), paint thinner, etc. Once the product has
cured, it can only be removed physically by scraping, buffing, etc. Dispose as plastic waste (foam plastic) in accordance with all
applicable guidelines and regulations.
114. Transport Information I
DOT UN/NA Number:
DOT Proper Shipping Name:
DOT Technical Name:
DOT Hazard Class:
Hazard SubClass:
Packing Group:
UN3500
Chemical under pressure, n.o.s.
(trans-1,3,3,3-Tetrafluoroprop-l-ene, trans-l-Chloro-3,3,3-trifluoropropene)
2.2 Non-flamm compressed gas
N.A.
N.A.
115. Regulatory Information I
SARA SECTION 313: : —AMW
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Polymeric diphenylmethane diisocyanate
4,4'-Methylene diphenyl diisocyanate (MDI)
CAS -No.
9016-87-9
101-68-8
TOXIC SUBSTANCES CONTROL ACT:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
Page 5 / 6
SIDS Number: 4800001 SAP Number: 9700050921 Revision Date: 5/4/2021
Revision Date:
Reason for revision:
Datasheet produced by:
HMIS Ratings:
Health: Flammability:
2-
5/11/2021
HazCom2012/GHS Conversion
Regulatory Department
Reactivity:
Supersedes Date: 3/15/2021
Personal Protection:
VOC Less Water Less Exempt Solvent, g/L:
VOC Material, g/L:
VOC as Defined by Cafrfornia Consumer Product Regulation, Wt/Wt%:
VOC Actual, Wt/Wt%:
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H319
Causes serious eye irritation.
H332
Harmful if inhaled.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335
May cause respiratory irritation.
H351
Suspected of causing cancer.
H373
May cause damage to organs through prolonged or repeated exposure.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS07
GHS08
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
M
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly
trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific
context of the intended use and Ili) determine if they are appropriate.
Page 6 / 6
Page:1
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Revision: 06/27/2017
Printing date 06/2712017
1 Identification -
Product identifier
Trade name: DAP Foam Inc Foam Side A
Product code: EHS 2212, 2632. 2732, 3131
Recommended use and restriction on use
Recommended use: Polyurethane -sealant
Restrictions on use: See Sections 8 and 10 for further information.
Details of the supplier of the Safety Data Sheet
Manufacturer/Supplier:
DAP Foam, Inc.
307 Integram
Pacific, MO 63069
Phone: (600) 325-6180
Emergency telephone number:
Infotrac Inc
(800)535-5053.+1 (352)323-3500
2 Hazard(s) identification�t;
9
Classification of the substance or mixture
Press. Gas
H280
Contains gas under pressure; mayexploda if heated.
Acute Tox. 4
H332
Harmful if inhaled.
Skin Irrit. 2
H315
Causes skin irritation.
Eye Irrit. 2A
H319
Causes serious eye irritation.
s or breathing difficulties if inhaled.
Resp. Sens. 1
H334
May cause allergy or asthma sym ptom
Skin Sens. i
H317
May Cause an allergic skin reaction.
STOT SE 3
H335
May cause respiratory irritation.
STOT RE 2
H373
May cause damage to organs through prolonged or repeated exposure.
Label elements
GHS label elements (GHS
The product is classified and labeled according to the Globally Harmonized System
Hazard pictograms:
.✓
GHSO4 GHS07 GHS08
Signal word: Danger
Hazard statements:
H280 Contains gas under pressure; may explode if heated.
H332 Harmful if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation. tConrd on page 21
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Printing date: 06/2712017
ur....=i�r-m�gG7JH.Y•Iill�Iii�
Page: 2
Revision: 06/27/2017
H373 May cause damage to organs through prolonged or repeated exposure. (Goned. of page 7)
Precautionary statements:
P260
Do not breathe mist/vapors/spray.
P284
P264
In case of inadequate ventilation wear respiratory protection.
Wash thoroughly after handling.
P280
Wear protective gloves and eye protection.
P271
Use only outdoors or in a well -ventilated area.
P272 Contaminated work clothing m ust not be allowed out of the workplace.
P305+P351+P338 If in eyes: Rinse cautiouslywith water for several minutes.
Remove contact lenses if
present and easy to do. Continue rinsing.
P302+P352
IF ON SKIN: Wash with plenty of water.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311
If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P312
Call a POISON CENTER/doctor if you feel unwell.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
P337+P313
P362+P364
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
P405
Store locked up.
P410+P403
Protect from sunlight. Store in a well -ventilated place.
P403+P233
Store in a well -ventilated place. Keep container tightly closed.
P501
Dispose of contents/container in accordance with local/regionallnational/international
regulations.
Other hazards There are no other hazards not otherwise classified that have been identified.
3 Compositiontinformation on ingredients
Chemical characterization: Mixtures
C
- — —
omponenis: ------'._
9016 87 9 diphenylmethanedusocyanate isomeres and homologues
Resp. Sens 1 H331; STOT RE 2, H373
Acute Tox. 4 H332, Skin Irrit. 2, H315: Eye Irrit. 2, H319, Skin Sens.
STOT SE 3, H335
101 68 8 4,4'--meth ylenediphenylditsocyanate _ -
< Pesp- Sens 1 H334; STOT RE 2 H373
t Acute Tox. 4 H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319: Skin Sens.
STOT SE 3, H335
5.
50-1000,11
H317;
- 25-50%
H317;
811-97-2flurane -- -_
_ ... -- - - - 1
Press. Gas, H280 0-25%a
Simple Asphyxiant
-Ad--di--tional i----- r- - _
nformation:-
For the listed ingredient(s), the identity and/or exact percentages) are being withheld as a trade secret.
For the wording of the listed Hazard Statements refer to section 16.
(Cont'd. on page 3)
Page:3
Safety Data Sheet
acc. to OSHA HCS (29 GFR 1910.1200) and WHM IS 2015 regulations
Revision: 06/27/2017
Printing date: 06/27/2017
Trade name: DAP Foam Inc Foam Side A
(Coned. of page 2)
4 First -aid measures
Description of first aid measures
General information:
Take affected persons out into the fresh air.
Do not leave affected persons unattended.
Symptoms of poisoning may even occur after several hours: therefore medical observation for at least 48
hours after the accident.
l After inhalation:
Supplyfresh air and to be sure to call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
I Do not pull solidified prod,ict awayfrom the skin.
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
j After eye contact:
� Protect unharmed eye.
Remove contact lenses if worn. toms ersist, consult a doctor.
Rinse opened eye for several minutes under running water. If symp p
After swallowing: j
Unlikely route of exposure.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting: immediately call for medical help.
Most important symptoms and effects, both acute and delayed:
Asthma attacks
Headache
Breathing difficulty
Coughing
Allergic reactions
Irritant to skin and mucous membranes.
Irritant to eyes. '
May cause respiratory irritation.
Danger:
Danger of impaired breathing.
Danger of convulsion. l
Condition in aydeteriorate with alcohol consumption.
May cause damage to organs through prolonged or repeated exposure.
Indication of any immediate medical attention and special treatment needed: i
Severe allergic skin reaction, bronchiai spasms and anaphylactic shock are possible.
Medical supervision for at least 48 hours.
If necessary oxygen respiration treatment.
Later observation for pneumonia and pulmonary edema.
Treat skin and mucous membrane with antihistamine and corticoid preparations.
Contains diphenylmethanediisocyanate,isomeres and homologues,4,4'-methylenediphenyldiisocyanate
May produce an allergic reaction.
i In cases of it to the lungs: initial treatmentwith cortical steroid inhalants. _ J
(Cont'd. on p€ge 4)
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Printing date: 06/27/2017
Page:4
. ..�•.,w u. vwaucv i!
Trade name: DAP Foam Inc Foam Side A
(Cont'd. of page 3)
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistantfoam.
For safety reasons unsuitable extinguishing agents: None.
Special hazards arising from the substance or mixture
Danger of receptacles bursting because of high vapor pressure if heated.
Advice for firefighters
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
Additional information: Cool endangered receptacles with water spray.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Use respiratory protective device against the effects of fumes/dust/aerosol.
Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
Protect from heat.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Allow to solidify. Pick up mechanically.
Clean the affected area carefully suitable cleaners are:
Warm water and cleansing agent.
Dispose contaminated material as waste according to item 13.
Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information
7 Handling and storage ,
Handling
Precautions for safe handling: Use only in well ventilated areas.
Information about protection against explosions and fires:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 120 OF / 49 °C,
i.e. electric lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressutized containers.
Avoid storage near extreme heat, ignition sources or open flame.
Page 5
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Revision: 06/27/2017
Printing date: 06/2712017 _ ---
Trade name: DAP Fo^m Inc Foam Side A
('Q 6 u. y� P.U. tj
Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with acids.
Store awayfrom oxidizing agents.
Further information about storage conditions:
Store in a cool place. Heat will increase pressure and maylead to the receptacle bursting.
Specific end use(s): No relevant information available.
8 Exposure contrails/personal protection
Control parameters
-
Componentswith limit values that require monitoring at the workplace:
101-668-84,4'-methylenediphenyl diisocyanate
PEL (USA) Ceiling limit value: 0.2 mg/m'' 0.02 ppm
REL (USA) Long-term value: 0,05 mg/m3, 0,005 ppm
Ceiling limit value: 0.2' mg/m', 0.02' ppm
.10-min
TLV (USA) Long-term value: 0.051 mg/m', 0:005 ppm
EL (Canada)
Long-term value:
0.005 ppm
Ceiling limit value: 0.01 pom
Skin; S
EV (Canada)
Long-term value:
0,005 ppm
Ceiling limit value:
0.02 ppm
LMPE (Mexico)
Long-term value:
0.005 ppm
811-97.2 Norflurane
W EEL (USA)
Long-term value:
1000 ppm
Exposure controls
Personal protective equipment:
General protective and hygienic measures: Keep away
from foodstuffs, beverages and feed. Immediately
remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work.
Avoid contact with the eyes and skin.
Engineering controls: Use only outdoors or in a well -ventilated area.
Breathing equipment:
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when high concentrations are present.
Protection of hands:
AIMPIX
Protective gloves
The glove material has to be impermeable and resistantto the product/ the substance; the preparation.
Gloves should provide protection from Freezing temperatures. (Cont'd. on page 6)
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHIM IS 2015 regulations
Printing date: 06/27/2017
Trade name: DAP Foam. Inc. Foam Sid a
Page:6
R2vicinn nR/97/9/117
Eye protection: (Cont'd. of page 5)
Contact lenses should not be worn.
® Safetyglasses
Body protection: Impervious protective clothing
Limitation and supervision of exposure into the environment
No relevant information available.
Risk management measures See Section 7 for additional information.
9 Physical and chemical properties
Information on basic physical and chemical properties
Appearance:
Form:
Aerosolized liquid with compressed gas in cylinders
Color:
Cream colored
Odor:
Characteristic
Odor threshold:
Not determined.
pH -value:
Not determined.
Melting point/Melting range:
Notcletermined.
Boiling point/Boiling range:
Not applicable, as aerosol.
Flash point:
Not applicable, as aerosol.
Flammability (solid, gaseous):
Notdetermined.
Auto -ignition temperature:
Not determined.
Decomposition temperature:
Not determined.
Danger of explosion:
Not determined.
Explosion limits
Lower:
Not determined.
Upper:
Not determined.
Oxidizing properties:
Not determined
Vapor pressure at 20 °C (68 OF):
5716 hPa (4287 mm Hg)
Density at 20 °C (68 OF):
1.03 g/cm' (8.595lbs/gal)
Relative density:
Not determined. I
Vapor density:
Not determined.
Evaporation rate:
Not applicable.
Solubility in I Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient(n-octanol/water): Not determined.
Viscosity — -- - - -
Dynamic: Not determined.
(Cont'd. on page 7)
Page:7
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Printing date: 06127/2017
Trade name: DAP Foam Inc Foam Side A
Kinematic: Not determined.
Other information No relevant information available.
10 Stability and reactivity.'
Reactivity: No relevant information available.
Chemical stability: Stable under normal temperatures and pressures.
Thermal decomposition / conditions to be avoided:
Danger of receptacles bursting because of high vapor pressure if heated.
Possibility of hazardous reactions:
Reacts with catalysts, oxidizing agents and strong alkali.
Reacts with strong acids and oxidizing agents.
Exothermic polymerization.
Conditions to avoid: Store awayfrom oxidizing agents.
incompatible materials: No relevant information available.
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Ammonia
11 Toxicological information
information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
101-68-84,4%methylenediphenyl diisocyanate
oral LD50 2200 mg/kg (mouse)
Primary irritant effect:
On the skin: Irritant to skin and mucous membranes.
On the eye: Irritating effect.
Sensitization: May cause sensitisation by inhalation and skin contact.
IARC (International Agencyfor Research on Cancer):
Norte of the ingredients are listed.
NTP (National Toxicology Program):
None of the ingredients are listed.
OSHA -Ca (Occupational Safety & Health Administration)
None of the ingredients are listed.
Probable route(s) of exposure:
Inhalation.
Eye contact
Skin contact.
Acute effects (acute toxicity, irritation and corrosivity):
Harmful if inhaled.
Revision: 06/27/2017
(Conrd_of pageo)
i
(Cont'd. on page B)
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Printing date: O6/27/2017
Page:&
Ravicin, nR/'77/9n1 7
Trade name; DAP Foam Inc Foam Side A
i
Irritating to eyes, respiratory system and skin. (Conrd. of page r)
Repeated dose toxicity: Possible risk of irreversible effects.
CMR effects (carcinogenity, mutagenicity and toxicityfor reproduction)
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
STOT-single exposure: Maycause respiratory irritation.
STOT-repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: Based on available data, the classification criteria are not met.
12 Ecological inform
Toxicity
Aquatic toxicity The product contains materials that are harmful to the environment.
Persistence and degradability The product is partially biodegradable. Significant residuals remain.
Bioaccumulative potential: Does not accumulate in organisms
Mobility in soil: No relevant information available.
Additional ecological information
General notes:
This statementwas deduced from products with a similar structure or composition.
Due to available data on elim inability/decom position and bioaccumulation potential prolonged term
damage of the environment can not be excluded.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Results of PST and vPv8 assessment
PST: Not applicable.
vPvB: Not applicable.
Other adverse effects: No relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Can be disposed of with household garbage after solidification following consultation with the waste
disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
Uncieaned packagings
Recommendation: Disposal must be made according to official regulations.
(Cont'd. on paga_ 9)
Page:9
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910,1200) and WHMIS 2015 regulations
Revision: 06127/2017
Printing date: 06/27/2017
Trade name: DAP Fo-m Inc Foam Side A
'_._- - ----- (Cont'd of page S)
14 Transn' --
LIN-Number T --- - - UN3500
DOT, ADR, IMDG, IATA _ - ---
UN proper shipping name
Chemical under pressure, n.o.s. (Fluorinated
DOT, IATA j
Hydrocarbon, Nitrogen)
ADR 3500 CHEMICAL UNDER PRESSURE, N.O.S. II
(Fluorinated Hydrocarbon, Nitrogen)
IMDG CHEMICAL UNDER PRESSURE, N.O.S. (Fluorinated
Hydrocarbon, Nitrogen)
i
Transport hazard class(es)
DOT
Class 2.2
Label 2.2
ADR
I
I _
2 8A Gases
Class
2.2
Label
IMDG, IATA
VOW
Class
22
22
Label
This UN -number is not assigned a packing group.
Packing group
i
Environmental hazards
I
Marine pollutant:
No
j
Special precautions for user
Warning: Gases
Danger code (Kemler):
20
EMS Number:
F-D.S-U
F-
Transport in bulk according to Annex H of
MARPOL73/78 and the IBC Code
Not applicable.
(Cont'd. on Page 10).
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations
Printing date: 06/27/2017
- • - M L . L . - I I r - ;
Page:10
Revision: 06/2712017
(Cont'd. of page 9)
Safety, health and environmental regulations/legislation specific for the substance or
mixture
United States (USA)
SARA
- --aza----
- ...
ection 302 (extremely-hrdous- -
substances): - -
None of the ingredients are listed.
Section 355 (extremely hazardous substances):
None of the ingredients are listed.
Section 313 (Specific toxic chemical listings):
9016-87-9 diphenylmethanediisocyanate.isomeres and homologues
101-68-8 4,4'-methylenediphenyidiisocyanate
TSCA(Toxic Substances Control Act) -----
All ingredients are listed. _
Proposition 65 (California)
Chemicals known to cause cancer:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are fisted.
i
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
Carcinogenic categories
EPA (Environmental Protection Agency): -- ---
9016-87 9 diphenylmethanediisocyanate.isomeres and homologues CBD
101-68 8 4,4'-methylenediphenyldiisocyanate ARC ----
RC (Intemational Agency for Research on Cancer): D, c-
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues -
3
101-68-8 4,4'-methylenedphenyldiisocyenate - ---------
3
NIOSH-Ca (National Institute for Occupational Safety and Health): -
None of the ingredients are listed.
Canadian Domestic Substances List (DSL):All ingredients are listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
(Cont'd. on page 11)
Page: 1 'I
Safety Data Sheet
acc. to OSHA FIGS (29 CFR 1910.1200) and IPJHMIS 2015 regulations
Printing date: 06i27/20'17
Trade name DAP FQam.Jnic.Foa_m Side A - - —
Revision: 06/27/2017
(Conrc of page 10)
16 Other information
This Inform ation, is based on our present knowledge. However, this shall not constitute a guarantee for any
specific prod! Ict features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision 07/07/2016 /
Abbreviations and acronyrrts:
ADR European Agie?ment concenn.ry the International Carriage or Dangerous Goads by Road
(MDG'. tnternanonal Maritime Code for Dangerous Goods
DOT: US Deparment of Transporation
AT.A. Interne Donal Air Trans'cen. Association
CAS: Chemical Abstracts Sarvir_e (division of the Amencan Chemical SO --Ill;)
LC50: Lethal concentration. 50 parnent
LD50 Lethal dose. 50 percent
PST: Persistent eioarcam ulative and Towc
vPrB. very Persistent and very ^oioaccum,ila Csa
NICSH National Institut� for Ociupauonal saf=ty
OSHA Occupational Safety & H?alln
LDLo: Lo�%est Lethal Dose Olc .awed
Press Gas. Gases under pressure - Compressed gas
Acute Tox. 3. Acute toxicity - Category 4
Skin brit. 2: Skin ccrrosionnrritation - Categoni 2
Eye brit. 2: Serious aye tlarnage;eya irn,aoon - Category 2
Eye brit. 2A. Serious eye dainage%eye imtatinn - Category 2.A
Resp, Sens 1: Respiratory sensdisabon- Cat=gory I
S's,n San;. 1: Shin sensRisaVon - Category 1
STOT SE 3 Specific target orgen tonicity (single a>p.lsurei - Categerr 3
STCT RE ) Spe.,ific target organ toxicity (repeated exposure) - Category -
Sources
iNebsite, European Chemicals Agency (echa.europa eu1
1Nebsite. US EPA Substance Registry Seri (ofmpub.epa_govlsorint.ernes/registrylsubstreg/home/
overview/home.do)
tNebsite, Chemical Abstracts Registry. American Chemical Soclety (wa'Vvl cos org)
Patty's industrial Hygiene, Stir ed Rose. Vemon, ed. ISBN: ISSN. 978-0-470-07488-6
CasareU and DOLIII's Toxicology: The Basic Science of Poisons, 8fh Ed. Klaasen, Curtis D., ed., ISBN.
978-0-07-176923-5.
Safety Data Sheets. individual Manufacturers
SDS Prepared by:
ChemTal inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
website: ;,AAvN.chemtelinc.conn
9704520104